There are two choices you have for claiming your car expense. You can either claim "actual expense" or you can take the "per mile" amount.
With "actual expense" you list the deprecation, repairs, gas, insurance, tags and maintenance costs. As an example, lets say that for 2008 you drive 20,000 miles. Lets say your vehicle expenses (including depreciation, gas etc.) are $8,000. Your mystery shopping miles of those 20,000 are 10,000. You would get a deduction of about half of your expenses. Since many of us get our maintenance (oil changes) on shops and are reimbursed that expense, we need to be careful and not "double dip" by also claiming it as part of our "actual expense". Similarly the gas we pick up on shops as a requirement we need to be careful not to "double dip" with.
With the "per mile" amount, IRS has set up 50.5 cents per mile for 2008. This number is supposed to cover the usual costs of insurance, tags, depreciation, gas and repairs etc. With this method there is no question about how you accomplished the task--whether your oil changes and gas were shop reimbursements.
While it may be that with a new car the "actual expense" method may be more beneficial to you, it is important also to think about how you use a car. If you drive a car for only two or three years and trade it in, "actual expense" may work for you over the long haul. If, on the other hand, you drive a car for 6-10 years it probably is better to use the "per mile" method because depreciation under "actual use" is highest in the first couple of years.
Once you decide on a method you are not allowed to change methods in subsequent years.
Parking expenses and tolls are a separate line item so are not included as part of either of the methods mentioned above.