Each company has their own 'schedule' for posting and most do not share when that is. There is one company I check shortly after midnight, another company generally posts late Saturday night, another company posts every other Monday around 2PM, another one posts generally early in the day the last working day of the month, others post when they jolly well please and one states on their website when they START posting but the jobs in my area generally post on day 2 or 3 or thereafter. So no, there is not one 'best' time or 'best' day because there is no 'one size fits all'.